人工防汛石材的碱激发制备及其抗冻性研究

Alkali activated preparation and frost resistance of artificial flood control stone

  • 摘要: 大块石稀缺是黄河流域防汛抢险的关键问题,而黄河泥沙的资源化利用是解决该问题的重要途径。通过碱激发资源化利用黄河泥沙,采用室内压制成型、现场碾压成型制备人工防汛石材,并用快速冻融法研究人工防汛石材的抗冻性能。采用扫描电镜(SEM)、X射线衍射(XRD)和压汞(MIP)等微观测试方法,研究人工防汛石材形貌、组成和结构的变化,阐明其微观作用机理。研究表明:随着添加剂掺量的增加,人工防汛石材抗压强度呈先提高后降低的趋势;抗压强度、质量、相对动弹性模量随冻融次数的增加而降低,碱激发水泥基人工防汛石材的抗冻性好于碱激发非水泥基人工防汛石材的抗冻性,极限冻融循环次数分别为80和40次;冻融循环不会引起碱激发防汛石材物相的变化,但会导致孔隙率增加,最可几孔径增大。碱激发制备的人工防汛石材具有良好的抗压强度,满足防汛抢险的使用要求。

     

    Abstract: The resource utilization of the Yellow River sediment and the scarcity of boulders in the process of flood control are two important problems to be solved. In this study, artificial flood control stone was prepared by using alkali activated resource utilization of Yellow River silt, indoor compaction and on-site compaction, and the frost resistance of artificial flood control stone was studied by rapid freeze-thaw method. In addition, scanning electron microscope (SEM), X-ray diffraction (XRD) and mercury intrusion (MIP) were used to study the changes of morphology, composition and structure of artificial flood control stone, and clarify its micro mechanism. The results show that the artificial flood control stone prepared by alkali excitation has good compressive strength, which meets the requirements of flood control and emergency use; with the increase of alkali activator content, the compressive strength of artificial flood control stone firstly increases and then decreases; with the increase of freeze-thaw times, the compressive strength, mass and relative dynamic modulus of elasticity of artificial flood control stone decrease gradually; the frost resistance of alkali activated cement-based artificial flood control stone is better than that of alkali activated non cement-based artificial flood control stone, and the limit freeze-thaw cycles are 80 and 40 respectively; and the freeze-thaw cycle will not change the phase of alkali activated flood control stone, but will increase the porosity and the most probable pore size.

     

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